Will this fit a Tele neck Position?

These pickups are made to fit a Stratocaster style guitar. You can make it fit a Telecaster but you'll likely have to modify the pick guard. The screw holes won't line up and the dimensions of this pickup are bigger than a Telecaster single coil neck pickup.

250 or 500 k pots? And tone capacitor values? Also, how would you configure 1 extra switch (not the 5 way) to make all pickups single coil?

Definitely 500k pots with a .022 to a .033 cap. I can send you a diagram or you can just go to the Seymore Duncan site for drawings.

What does splitting the coils do ?

It gives you a strat kinda sound I'm using It with 2 hamburgers on a stratocaster but chose the 9 ohm version because I'm using it in the middle it is a very good pickup for the money you don't find many alnico v blade pickups its definitely usable.

Item Weight	59 g
Product Dimensions	8.33 x 2.41 x 2.01 cm; 59 g
Body Material	Metal
Color Name	Black (Full Black)
Guitar Pickup Configuration	H
Number of Strings	6
Material Type	Alnico V
Size	13-14K

Alnico 5 Hot Dual Rail Humbucker Single-Coil-Sized Pickup 12-13K Humbucker Pickup, Full Black

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