What's the shelf life of this product once opened?

Around 3 years. I bought mine last year and it will expire in 2018. Excellent product. I will keep buying it

Does this come in a plastic or glass bottle?

It comes in a BPA-free plastic bottle

I understand the calcium is "from" calcium chloride, does that mean there are chloride ions in this supplement also?

No, it is elemental (pure) calcium sourced from calcium chloride.

1/2 cap contains 144mg or 400mg of elemental calcium?

Hello, One 1/2 cap contains 400 mg of Calcium. Thank you for your question!

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Ionic Calcium | Natural | Nano Sized Mineral Technology | Professional Grade | Supports Healthy Bones, Tendons & Ligaments | 96 Servings at 400 mg | 8 Fl oz Bottle

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